Trimethylenemethane-Reactivity and Stereochemistry
نویسندگان
چکیده
منابع مشابه
Photoelectron Spectroscopy of the Trimethylenemethane Negative Ion
The photoelectron spectrum of the trimethylenemethane (TMM) negative ion is described. The electron affinity of TMM is found from the spectrum to be 0.431 6 0.006 eV, and the energy difference between the X̃ A9 2 and b̃ A1 states of TMM is determined to be 16.1 6 0.2 kcal/mol. The energy difference between the lowest energy triplet and singlet states is estimated to be 13–16 kcal/mol. The enthalp...
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Upon ionization by gamma-irradiation in frozen CFCl(3), or by X-irradiation in an Ar matrix, 2,2,3,3-tetramethylmethylenecyclopropane (MCP-Me4) readily undergoes ring opening to yield the radical cation of 1,1,2,2-tetramethyltrimethylenemethane (TMM-Me4). The hyperfine-coupling constants for TMM-Me4(.+) are (mT) -1.99 (2H), +0.53 (6H), and +0.19 (6H), and the singly occupied orbital closely res...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1973
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.31.635